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Roll the brass on a table to ascertain that the primer pockets are concentric. As to timing, it is easy to check on an unloaded gun. Either SA or DA, pull the trigger back and hold tension on it. There should be zero rotational play in the cylinder. Now, ease the trigger forward 1/8" or so and you should have a touch of rotational play - about like non-Colt revolvers normally do. Pull the trigger back again and you should be able to watch the hand rotate the cylinder a few thousandths into exact alignment with the barrel. They are tuned and timed so that when the trigger is all the way back, the hand pre-loads the cylinder against the bolt, and the bolt against the left edge of its window in the frame. If it does that on all six chambers, the timing is good.